What is Pulsed Laser Deposition (PLD)?

Introduction to Pulsed Laser Deposition (PLD):8 Applications

An Overview of Pulsed Laser Deposition

Pulsed laser deposition is a physical vapor deposition technique in which a high-energy laser is focused on a target material in a vacuum chamber and converted to a plasma plume, which is deposited on a substrate (Figure 1). The deposition can be assisted by a flow of oxygen or other background gases, or occur under ultra-high vacuum conditions.

While the equipment needed to perform the deposition in this manner is roughly similar to other deposition methods (such as sputtering), the physical interaction between the laser beam and the target material and the formation of the thin film is very complex. Absorption of laser pulse energy by the target causes electron excitations, which can convert to thermal, chemical, and mechanical energy and evaporation of the target material.

Pulsed Laser Deposition Shematic
Figure 1. Schematic of a PLD Device

The evaporated energetic particles, including atoms, molecules, ions, and electrons can form a plasma plume that will be deposited on the substrate.

The precise mechanism of the PLD process is complex, including the process of target material ablation by laser irradiation, the creation of plasma plumes with energetic ions, electrons, atoms, molecules, and charge-free particles, and the process of crystalline growth on the substrate.

Pulsed Laser Deposition (PLD) Process

The pulsed laser deposition process can be divided into four steps, each having a significant impact on the crystallinity, uniformity, and stoichiometry of the created thin film (Read more about Thickness Uniformity).

  • Absorption of the laser on the target surface and interaction with the material, ablation, and plasma formation
  • Plasma dynamics and laser-plume interactions
  • Deposition of the material separated from the target on the substrate.
  • Nucleation and growth of a thin film of the material on the substrate surface

Laser-Target Interaction

In the first phase, the laser beam is adsorbed on the target surface. Using sufficient high energy density and short pulse duration causes sudden heating up of all elements in the target surface to their evaporation temperature, where they are dissociated from the target by collisional, thermal and electronic excitation, and exfoliation and instantaneously ablated out with the same stoichiometry as the target.

Plasma Plume Formation

In the second stage, the ablated materials have a tendency to move towards the substrate according to the dynamic laws of gases and show the forward peaking phenomenon, creating a plasma plume.

Deposition on the Substrate

The high-energy species in the plasma plume impinge onto the substrate surface through the third stage. These energetic species sputter some of the atoms deposited on the substrate surface and a region is established where the incident flow and the sputtered atoms collide. Film growth happens directly next to this collision or thermalized region. This region condensates the energetic particles, so they can be deposited on the substrate (Figure 2).

Schematic Diagram of Plasma-Substrate Interaction
Figure 2. Schematic Diagram of Plasma-Substrate Interaction

Nucleation and Growth

The Forth stage, nucleation and growth of the crystalline thin films depends on many factors such as the density, energy, degree of ionization, the type of the condensing material, temperature, and the properties of the substrate. The nucleation process is influenced by the interfacial energies between the substrate, condensing material and the vapor. Deposition rate and the substrate temperature greatly affect the critical size of the nucleus. Large nuclei create isolate islands of the film on the substrates that grow and join together (Figure 3).

The crystalline film growth is determined by the surface mobility of the deposited atoms, which diffuse on the surface before fixing onto a stable position, highly dependent on the temperature of the substrate. Defect free crystal growth can occur at high temperatures, whereas deposition on a low temperature substrate may result in poor crystalline or even amorphous structure.

Thin Film Growth Steps
Figure 3. Thin Film Growth Steps

Which Laser is Used in PLD?

Each step in the PLD process is dependent on the target material, laser parameters like wavelength, fluence and pulse width, substrate, temperature, and deposition geometry. Wavelength of the lasers used in PLD studies ranges from the mid-infrared, like CO2 laser with a wavelength of 10.6 µm, through the near-infrared and visible, such as Nd-YAG laser with output wavelengths at 1064 nm and 532 nm, down into the ultraviolet. Most of the current PLD work employs excimer lasers operating at different UV wavelengths, e.g. 308 nm (XeCl), 248 nm (KrF), 193 nm (ArF), and 157 nm (F2).

The laser pulse should penetrate the surface of the target material to a specific penetration depth. The depth of penetration depends on the laser wavelength and refractive index of the target material at the laser wavelength. For most materials, this depth is about 10 nm. The strong electric field created by the laser beam causes the electrons to separate from the bulk. This process is performed in a pulse of 10 picoseconds or nanoseconds and occurs due to nonlinear processes such as multi-photon ionization.

PLD: Advantages and Disadvantages

PLD technique has several advantages that make it straightforward for thin film deposition, such as:

  • Retaining the target stoichiometry in the deposited film
  • Need to control only a few parameters related to the laser during the deposition, like laser energy density and pulse repetition rate
  • Small targets required compared to other sputtering techniques
  • Ability to produce multi-layered films of different materials by sequential ablation of various targets
  • Controlling film thickness down to atomic monolayer by manipulating the number of pulses
  • Lower substrate temperature needed compared to other deposition techniques

Main Disadvantages of Pulsed Laser Deposition Technique

However, several limitations in producing large area uniform thin films by pulsed laser deposition method have been identified that are listed below:

  • Splashing or deposition of micrometer-sized particulates on the films because of sub-surface boiling, expulsion of the liquid layer, and exfoliation of the target
  • Narrow angular distribution of the ablated species by the laser

Though these issues can be overcome by inserting a shadow mask to block off the large particulates, or rotating the target and substrate to produce larger uniform films, such shortcomings have hindered fully utilizing PLD in industry.

Pulsed Laser Deposition of Thin Films

Several techniques have been developed in PLD to obtain thin films with higher quality, grow thin films of targets made of polymers or biomaterials, deposition of multi-component targets and several multiple targets. Some of them are explained here.

PLD Methods

Scanning Multi-Component Pulsed Laser Deposition

In this method, a desired composition of various segments of the target containing different materials can be deposited by moving the scan line concerning the target geometry. This results in large area and uniform deposition of multicomponent coatings (Figure 4).

Scanning Multi-Component Pulsed Laser Deposition
Figure 4. Scanning Multi-Component Pulsed Laser Deposition

Combined PLD and Magnetron Sputtering

By combining PLD and magnetron sputtering (MS), the magnetron discharge can be maintained at lower pressures compared to a typical MS system, which results in higher deposition rates and direct deposition of clusters, and neutral atomic species by PLD (Figure 5).

Combined PLD and Magnetron Sputtering
Figure 5. Combined PLD and Magnetron Sputtering

Matrix Assisted Pulsed Laser Evaporation (MAPLE)

It is a useful method to deposit frozen targets of inorganics, polymers, and biomaterials dissolved in a volatile solvent, which adsorbs high energy laser beam and prevents damage to the material molecules. Target molecules are heated up through collision with solvent molecules and convert to vapor phase, where solvent vapor is easily pumped out due to their lower adhesion coefficient (Figure 6).

Matrix Assisted Pulsed Laser Evaporation
Figure 6. Matrix Assisted Pulsed Laser Evaporation

Multi-Beam PLD

This PLD method is mainly used to deposit a thin film from multi-targets of different materials by mixing more than one plasma plume during thin film deposition (Figure 7).

Multi-Beam PLD
Figure 7. Multi-Beam PLD

Off-Axis PLD

In off-axis PLD technique, the substrate is placed parallel to the plasma plume, which results in the deposition of thinner and more uniform films on the substrate compared to the on-axis substrate (Figure 8).

Off-axis PLD
Figure 8. Off-axis PLD

Pulsed Laser Deposition Applications

Pulsed laser deposition has attracted widespread interest since the successful growth of high-temperature superconducting films in 1987. This technique has been employed to fabricate various materials, including:

  • Epitaxy crystalline thin films
  • Nitride films
  • Metallic multilayers
  • Ceramic oxides
  • Superlattices
  • Nanotubes
  • Nanopowders
  • And quantum dots

Because of the high heating rate and lower substrate temperature in PLD compared to other deposition methods, semiconductors, and the underlying integrated circuits can be deposited through PLD.

VacCoat PLD

The VacCoat Co. PLD-T is a high vacuum thin film deposition system. This device is equipped with the target manipulator system with adjustable rotation speed. This pulsed laser deposition (PLD) system is capable of producing thin films of uniform composition and thickness in all substrate areas. It also has a vacuum thermal evaporation with three heat evaporation sources to perform thermal evaporation coating.

PLD-T is equipped with quartz crystal monitoring system for real time thickness measurement (1 nm precision), as well as a plasma cleaning option, rotatory sample holder and electronic shutter, that can be controlled by an intuitive touch screen to control the coating process and rapid data input with a updatable user friendly software. For more information visit the site of VacCoat Company.

Other Deposition Systems

References

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  2. Benelmekki, M., & Erbe, A. (2019). Nanostructured thin films–background, preparation and relation to the technological revolution of the 21st century. Nanostructured Thin Films, 1–34. doi:10.1016/b978-0-08-102572-7.00001-5
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